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GK QUESTION#3382

Which descending order follows the usual relative basic strengths of the conjugate-base ions nitrate (NO₃⁻), chloride (Cl⁻), bromide (Br⁻) and iodide (I⁻)?

  1. ACl⁻ > Br⁻ > I⁻ > NO₃⁻
  2. BNO₃⁻ > Cl⁻ > Br⁻ > I⁻Correct answer
  3. CI⁻ > NO₃⁻ > Cl⁻ > Br⁻
  4. DBr⁻ > I⁻ > NO₃⁻ > Cl⁻
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Answer

B. NO₃⁻ > Cl⁻ > Br⁻ > I⁻

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Explanation

The conjugate base of a stronger acid is weaker. Relative acid strength decreases through HI, HBr, HCl and HNO₃, so descending conjugate-base strength is nitrate, chloride, bromide, iodide. All four anions have negligible basicity in water; the ordering expresses relative strengths beyond water’s levelling effect.

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