GK QUESTION#3362
Assertion (A): When aqueous solutions of sodium sulphate and barium chloride are mixed, a white precipitate is formed.
Reason (R): Barium sulphate is insoluble in water and hence precipitates out.
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Answer
A. Both A and R are true, and R is the correct explanation of A
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Explanation
Mixing sodium sulphate and barium chloride solutions forms white barium sulphate: Na₂SO₄+BaCl₂→BaSO₄(s)+2NaCl. The net ionic process is Ba²⁺+SO₄²⁻→BaSO₄(s). Its very low solubility explains why it precipitates, so both the assertion and reason are true and the reason explains the assertion.