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GK QUESTION#3280

Consider the following statements regarding hydrides used in organic chemistry:

1. Calcium hydride is commonly used as a drying agent and can act as a reducing agent in some reactions.

2. Lithium aluminium hydride is primarily used as a drying agent in the laboratory.

Which of the statements given above is/are correct?

  1. AOnly 1Correct answer
  2. BOnly 2
  3. CBoth 1 and 2
  4. DNeither 1 nor 2
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Answer

A. Only 1

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Explanation

Calcium hydride reacts with residual water and is used to dry suitable organic solvents; it can also be used in reducing systems under appropriate conditions. Lithium aluminium hydride is chiefly a powerful synthetic reducing reagent, although it has also been used for drying some solvents. Thus statement 1 is correct and the claim that drying is its primary laboratory role is false.

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