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GK QUESTION#3240

Consider the following statements about chemical transformations of glucose: 1. The reduction of glucose using sodium amalgam leads to the formation of sorbitol. 2. The oxidation of glucose using acetic anhydride produces glucose pentaacetate. Which of the above statements is/are correct?

  1. AOnly 2
  2. BOnly 1Correct answer
  3. CBoth 1 and 2
  4. DNeither 1 nor 2
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Answer

B. Only 1

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Explanation

Reduction of the open-chain aldehyde group of glucose gives the polyalcohol sorbitol, also called glucitol; sodium amalgam is a traditional reducing reagent for this conversion. Acetic anhydride instead acetylates the hydroxyl groups to form glucose pentaacetate. That transformation is not oxidation, so only statement 1 is correct.

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