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GK QUESTION#3166

Which electrostatic theory treats ligands as charges or dipoles and explains geometry-dependent splitting of the metal d-orbital energies in coordination complexes?

  1. ACrystal field theory (CFT)Correct answer
  2. BLigand field theory (LFT)
  3. CValence bond theory (VBT)
  4. DMolecular orbital theory (MOT)
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Answer

A. Crystal field theory (CFT)

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Explanation

Crystal field theory models ligands as electrostatic charges or dipoles that remove the degeneracy of metal d orbitals. The splitting pattern depends on ligand geometry. The electrostatic qualification distinguishes CFT here from ligand field theory, which incorporates covalent bonding effects.

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